Cluster catalysed selective transfer hydrogenation of α,β-unsaturated aldehydes
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 173-174
- https://doi.org/10.1039/c39880000173
Abstract
H4Ru4(CO)8L4(L = PBu3 n) catalyses selective transfer hydrogenation of α,β-unsaturated aldehydes to α,β-unsaturated alcohols; kinetic and deuterium labelling studies indicate involvement of cluster intermediates and no participation by the cluster hydrides.Keywords
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