An octahedral rhenium(III) cluster: X-ray crystal structure of Na4Re6S10(S2)

Abstract
The reaction of Re, KReO4, or ReS2 with an excess of Na2CO3 or K2CO3 and S at 750 °C yields MI 4Re6S12, ReIII compounds containing Re6 octahedra located in cubes of sulphide ions with sulphide and disulphide bridges between octahedra.

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