Crystal and molecular structure of a new type of tetranuclear mixed valence copper complex: Cu4Ac6(Ph3P)4(Ac = O2CMe)
- 1 January 1984
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 381-383
- https://doi.org/10.1039/c39840000381
Abstract
The crystal structure of Cu4Ac6(Ph3P)4 comprises centrosymmetrical molecules, each of which consists of a dimeric unit of Cu2Ac4, similar to that in the structure of copper(II) acetate monohydrate, with the copper(I) co-ordinated through the oxygen atom of the acetate group in both axial CuAc(Ph3P)2 units.Keywords
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