Ligand-field calculations for cobalt(II) compounds
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 6,p. 724-728
- https://doi.org/10.1039/dt9720000724
Abstract
g Factors are calculated for tetragonal low-spin d7 complexes using a d3 hole ligand-field model. It is shown that the unpaired electron lies in the dz 2 orbital (i.e. that the ground state is Γ6 or 2A1) in all forms of cobalt phthalocyanine, as well as in vitamin B12r and its model compounds.Keywords
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