Kinetics of substitution at bis(2,2′-bipyridyl)biscyanoiron(II)
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 2,p. 203-206
- https://doi.org/10.1039/dt9720000203
Abstract
The kinetics of reaction of Fe(bipy)2(CN)2 with 1,10-phenanthroline have been investigated in water and in mixed aqueous solvents. Logarithms of rate constants for this reaction, and for the analogous reaction of a Schiff base complex Fe(SB)2(CN)2, where SB =N-(2-pyridylmethylene)-3,4-dimethylaniline, correlate linearly with Grunwald–Winstein solvent Y values. Reaction of Fe(bipy)2(CN)2 with hydroxide follows a first-order rate law with rates independent of hydroxide concentration.Keywords
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