Catalytic effect of a BH3: N,N-diethylaniline complex in the formation of alkenyl catecholboranes from alk-1-ynes and catecholborane
- 1 January 1990
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 446-447
- https://doi.org/10.1039/c39900000446
Abstract
Alkenyl catecholboranes are readily formed by the reaction of catecholborane and alk-1-ynes at 25°C, in the presence of 10 mol% of a BH3:N,N-diethylaniline complex, via a hydroboration–alkenyl transfer mechanism.Keywords
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