Abstract
The influence of the heat treatment and of the exciting wavelength, the correlation between the excitation and luminescence polarisations on the 4T2 to 4A2 no-phonon lines and broad-band emission of MgO:Cr3+ were studied. The results show that emission comes from only one level but is due to two processes, of which one corresponds to an electric dipole transition allowed in the C2v symmetry and the other corresponds to a transition which is forbidden, but assisted by vibrations.