Preparation and structure of Cs[TcN(O2)2Cl]; the first example of a nitridoperoxo complex
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1890-1891
- https://doi.org/10.1039/c39890001890
Abstract
Reaction of Cs2[TcNCl5] with hydrogen peroxide yields the chloronitridoperoxo complex Cs[TcN(O2)2Cl], which has been shown by single-crystal X-ray analysis to have a distorted pentagonal pyramidal co-ordination geometry with the nitrogen atom in the apical position.Keywords
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