Inversion of Excited States of Transition-Metal Complexes
- 11 December 1970
- journal article
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 170 (3963) , 1195-1196
- https://doi.org/10.1126/science.170.3963.1195
Abstract
The nature of the emission from central metal ions in complexes can be controlled by chemical alteration of the ligands. For iridium(III) species three types of emission have been observed, each originating from a different and orbitally identifiable excited state. Principles useful for designing new luminescent materials are formulated. They can be used for guiding photochemical research and for designing new analytical methods.Keywords
This publication has 4 references indexed in Scilit:
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- Luminescence of tris(2,2'-bipyridine)ruthenium(II) dichlorideJournal of the American Chemical Society, 1969
- Spectroscopic Studies of Ruthenium(II) Complexes. Assignment of the LuminescenceThe Journal of Chemical Physics, 1968
- Optical excitation of transition-metal ions via intramolecular energy transferJournal de Chimie Physique et de Physico-Chimie Biologique, 1967