Organocyanocopper-trifluoroborane mediated 1,3-chirality transfer reaction of .gamma.-(mesyloxy)-.alpha.-alkyl .alpha.,.beta.-enoates for the construction of chiral quaternary carbon centers with high optical purity
- 1 August 1989
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 54 (17) , 4055-4061
- https://doi.org/10.1021/jo00278a015
Abstract
No abstract availableThis publication has 4 references indexed in Scilit:
- Very high chemoselective, regioselective, and E-stereoselective 1,3-chirality transfer involving reaction of acyclic (E)- and (Z)-.gamma.-mesyloxy .alpha.,.beta.-enoates and organocyanocopper-trifluoroborane reagents. Efficient synthetic routes to functionalized chiral .alpha.-alkyl (E)-.beta.,.gamma.-enoates and (E)-allylic alcohols with high optical purityJournal of the American Chemical Society, 1989
- Total synthesis of natural (+)-sesbanimide a and (-)-sesbanimide bTetrahedron, 1988
- An asymmetric synthesis of 4,4- and 6,6-dialkylcyclohexenones and 4,4- and 5,5-dialkylcyclopentenones. Application to the total synthesis of (-)-silphiperfol-6-eneTetrahedron, 1987
- The stereoselective α-alkylation of chiral β-hydroxy esters and some applications thereofTetrahedron, 1984