Rearrangement of Tetramethyl-trans-decalin Derivatives
- 1 July 1975
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 48 (7) , 2221-2222
- https://doi.org/10.1246/bcsj.48.2221
Abstract
The dihydroxydecalin (6) was treated with iodine at 140 °C to give the octalins (13 and 14). Treatment of the β-epoxide (8) with boron trifluoride etherate gave the octalins [17 and 18 (or 19)] and the oxide (20).Keywords
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- Syntheses in the Terpene Series. V.1 A Synthesis of DL-1,1,6α,10β-Tetramethyl-trans-decal-2β-ol-5-one, the Racemate of a Degradation Product of α-AmyrinJournal of the American Chemical Society, 1958