Activation of arene carbon–hydrogen bonds. Direct electrophilic aromatic metallation with a rhodium–porphyrin complex
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 478-479
- https://doi.org/10.1039/c39830000478
Abstract
Anion exchange of octaethylporphyrinatorhodium(III) chloride with AgClO4 or AgBF4 results in the formation of a highly electrophilic RhIII–porphyrin capable of direct metallation of arenes.Keywords
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