Carbohydrate derivatives of 1-substituted 1,2,3-triazoles
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- p. 519-520
- https://doi.org/10.1039/j39670000519
Abstract
Hexosulose bis(benzoylhydrazones) were prepared from the corresponding osulose (osone) and benzoyl- or substituted benzoyl-hydrazines. Their tetra-O-acetyl derivatives were oxidised with iodine and mercuric oxide to 1-α-benzoyloxybenzylideneamino-1,2,3-triazoles. Deacetylation of the D-arabino-derivatives of the 1,2,3-triazoles afforded the 1,2,3-triazoles which on reacetylation gave 1-acetamido-4-(D-arabino-tetra-acetoxybutyl)-1,2,3-triazole.Keywords
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