RhCl(PPh3)3-catalyzed Coupling of Diorganomercurials
- 1 October 1977
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 50 (10) , 2741-2743
- https://doi.org/10.1246/bcsj.50.2741
Abstract
RhCl(PPh3)3 has been proved to be an effective catalyst for the reaction of various diorganomercurials to give such coupling products as conjugated diyne, conjugated diene, biaryl, and alkane in good yields under mild conditions. A probable mechanism including the oxidative addition of organomercurials to a rhodium complex and the subsequent reaction of two oxidative-addition adducts to yield the product was presented.This publication has 12 references indexed in Scilit:
- Organomercury compounds as synthetic intermediates. Coupling of arylmercuric saltsThe Journal of Organic Chemistry, 1976
- Mercury in organic chemistry. 7. A convenient synthesis of symmetrical conjugated dienes and polyenesThe Journal of Organic Chemistry, 1976
- Synthesis of C-5 substituted pyrimidine nucleosides via organopalladium intermediatesJournal of the American Chemical Society, 1976
- Hydrogenation and carbonylation of organomercury compounds catalyzed by Group VIII metal complexesThe Journal of Organic Chemistry, 1975
- The reaction between organomercurials and platinum(0) phosphine complexes: a new versatile synthesis of σ-bonded organoplatinum(II) compoundsJournal of Organometallic Chemistry, 1974
- Reaction of 2-alkenyl-1,3,2-benzodioxaboroles with mercuric acetate. Convenient stereospecific procedure for the conversion of alkynes into alkenylmercuric saltsJournal of the American Chemical Society, 1972
- Organoboranes : XIII. The mercuration of vinylboranes. A convenient stereospecific procedure for the conversion of acetylenes into vinylmercury salts via hydroboration-mercurationJournal of Organometallic Chemistry, 1972
- Oxidative coupling of toluene through organometallic intermediatesThe Journal of Organic Chemistry, 1969
- Redistribution and Exchange Reactions in Groups IIB-VIIBChemical Reviews, 1965
- THE PREPARATION OF MERCURY DIPHENYL1 BY USE OF THE GRIGNARD REAGENTJournal of the American Chemical Society, 1929