Addition of diethyl bromodifluoromethylphosphonate to various alkenes initiated by Co(III)/Zn bimetal redox system

1 January 1993

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1

No. 3,p. 327-330
https://doi.org/10.1039/p19930000327

Abstract

The addition of diethyl bromodifluoromethylphosphonate 1 to various alkenes 2 initiated by cobaloxime(III)/Zn bimetal redox system gives 1:1 Michael-type adducts 3 in moderate to good yields. A radical mechanism is proposed.

Keywords

DIETHYL BROMODIFLUOROMETHYLPHOSPHONATE
COBALOXIME
GOOD
RADICAL
ADDUCTS
MICHAEL
ALKENES INITIATED

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