The composition and magnetic properties of some iron(III) 1,10-phenanthroline and bipyridyl complexes
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1561-1564
- https://doi.org/10.1039/j19670001561
Abstract
The isolation of complexes of stoicheiometry [Fe2B4O]X2Y2·xH2O (where B = 1,10-phenanthroline, X = Y = Cl, ClO4, NO3, or ½SO4, or X = Cl, Y = ClO4, or B = bipyridyl, X = Cl, Y = ClO4) is reported. For the chloride complex co-ordination of chlorine to iron appears to occur. The magnetic properties of the complexes over the temperature range 80–300°K have been interpreted using a binuclear spin-free iron(III) model.Keywords
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