2,2‘;9‘,2‘ ‘-Ter[1,10]phenanthroline
- 23 July 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 44 (17) , 5984-5986
- https://doi.org/10.1021/ic050712w
Abstract
The title molecule, 2,2‘;9‘,2‘ ‘-ter[1,10]phenanthroline can be prepared from 2,9-dichloro-1,10-phenanthroline in three steps through the corresponding diacetyl intermediate. The ligand acts as a hexadentate with K+, while two molecules form a trinuclear, helical complex with Cu(I), which evidences π-stacking interactions and Cu−Cu distances of 3.01−3.04 Å. Electrochemical analysis shows a strong interaction between the Cu(I) centers.Keywords
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