Kinetics of High-Polymer Reactions: Effects of Neighboring Groups
- 15 January 1963
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 38 (2) , 318-321
- https://doi.org/10.1063/1.1733659
Abstract
A recurring problem in polymer chemistry is the dependence of functional group reactivities on the reacted-or-unreacted status of neighboring groups. This problem has been attacked by means of a closed-loop model and an infinite-chain model. For the latter model, an approximate solution has been developed for the general case, and an exact solution has been shown for the speical case where k1=k2.Keywords
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