Free radical addition to olefins. Part 8.—Addition of n-heptafluoropropyl radicals to fluoro-ethylenes
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 68, 160-166
- https://doi.org/10.1039/f19726800160
Abstract
The light-induced addition of perfluoropropyl iodide to fluoro-ethylenes in the gas phase C3F7·+ RCHCH2→ C3F7CH2ĊHR (2) has been studied, and activation parameters determined by a competitive method. The corresponding differences found are: [graphic omitted] The most striking feature is the similarity to the results for addition of bromotrichloromethane to the same olefins. Relationships between activation energies and some theoretical quantities are discussed.Keywords
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