Interception of alkylchlorocarbenes
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 775-776
- https://doi.org/10.1039/c39780000775
Abstract
Ethylchloro-, isopropylchloro-, and t-butylchloro-carbenes have been generated by photolysis of the corresponding 3-alkyl-3-chlorodiazirines and added to several alkenes; the partition between intermolecular interception and intramolecular liquidation of the carbenes was mainly dependent on the structure of the carbenic alkyl groups.Keywords
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