Deoxygenative Reduction of Diruthenium Carbonyl Complexes (η5-C5H4R)2Ru2(μ-CO)2(CO)2with Hydrosilanes Leading to Bridging Methylene Complexes (η5-C5H4R)2Ru2(μ-CH2)n(μ-CO)2-n(CO)2(n= 1, 2; R = H, CH3)
- 14 May 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 15 (10) , 2548-2553
- https://doi.org/10.1021/om950893h
Abstract
No abstract availableKeywords
This publication has 44 references indexed in Scilit:
- Deoxygenative Reduction of Dimolybdenum Carbonyl Complexes Mo2(.eta.5-C5H4R')2(CO)4 by Hydrosilane Giving Trinuclear .mu.3-Methylidyne and .mu.3-Ethylidyne Complexes, (.mu.3-CR)[Mo(.eta.5-C5H4R')(CO)2]3 (R, R' = H, CH3), and Analysis of the Rotational Processes of the Mo(.eta.5-C5H4R')(CO)2 MoietiesOrganometallics, 1995
- Formation of a Trinuclear .mu.3-Methylidyne Complex, (.mu.3-CH)[MoCp(CO)2]3, through Reduction of a CO Ligand in Cp2Mo2(CO)4 by a HydrosilaneOrganometallics, 1994
- Oxymethylation of alkyliron complex CpFe(CO)2-R with hydrostannane and -silane, leading to R-CH2OH derivatives: related reactions of CpFe(CO)(L)-R and CpFe(CO)(L)-C(O)R type organoiron complexes and the molecular structure of trans-CpFe(H)(CO)(SnPh3)2Organometallics, 1991
- Reduction of acyl ligand in transition-metal complexes by catalytic hydrosilylationOrganometallics, 1991
- Carbon monoxide and carbon dioxide fixation: relevant C1 and C2 ligand reactions emphasizing (.eta.5-C5H5)Fe-containing complexesChemical Reviews, 1988
- Transformations of carbon monoxide and related ligands on metal ensemblesAccounts of Chemical Research, 1988
- Trinuclear Osmium Clusters as Models for Intermediates in Carbon Monoxide Reduction Chemistry. 1. Stepwise Reduction of CO to a μ-CH2 Ligand on an Os3 Cluster FaceJournal of the American Chemical Society, 1984
- Organic chemistry of dinuclear metal centres. Part 4. µ-Carbene and µ-vinyl complexes of ruthenium from allenesJ. Chem. Soc., Dalton Trans., 1983
- Organometallic Aspects of the Fischer‐Tropsch SynthesisAngewandte Chemie International Edition in English, 1982
- Definitive identification of the structures of dicyclopentadienyldiiron tetracarbonyl in solutionJournal of the American Chemical Society, 1970