The rovibrational Raman spectrum of water vapourv1andv3
- 1 September 1978
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 36 (3) , 727-732
- https://doi.org/10.1080/00268977800101881
Abstract
The OH stretching region in the Raman spectrum of water vapour has been observed and reproduced by computer simulation using rovibrational wave functions derived from the analysis of high-resolution absorption spectra. Relative intensity measurements allow the determination of the depolarization ratio and the ratio of the two non-vanishing second-order irreducible tensor components for v 1. These quantities have been combined with the literature value for the cross section of this band to calculate the principal cartesian components of the v 1 derived polarizability tensor. The cross section for the v 3 vibration was also determined, and these results are considered in terms of the bond polarizability theory.Keywords
This publication has 14 references indexed in Scilit:
- The Rayleigh depolarization ratio and rotational Raman spectrum of water vapor and the polarizability components for the water moleculeThe Journal of Chemical Physics, 1977
- Raman spectra of asymmetric top moleculesMolecular Physics, 1977
- The ro-vibrational Raman spectrum of water vapour υ2 and 2υ2Molecular Physics, 1977
- The ν5 and ν3 Raman bands of CH2D2Journal of Molecular Spectroscopy, 1976
- Raman-scattering cross sections for water vaporJournal of the Optical Society of America, 1976
- Raman band contours for water vapor as a function of temperatureApplied Physics Letters, 1976
- Vibration-rotation intensities in H2O-type molecules application to the 2ν2, ν1, and ν3 bands of H216OJournal of Molecular Spectroscopy, 1975
- Raman spectra of asymmetric top molecules. Part 1.—The pure rotational spectrum of ethyleneJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1975
- The interacting states (020), (100), and (001) of H216OJournal of Molecular Spectroscopy, 1974
- The 2v2,v1andv3bands of H216OMolecular Physics, 1973