The Hydride Reduction of Hemiaminals of Thiobinupharidine and the Structure of Thionupharoline

Abstract
Thionupharoline has been shown to be identical with 6-hydroxythiobinupharidine. The hydride reduction of hemiaminals of thiobinupharidine has been examined in ethanol solution. The steric course of reduction at C-6 is not nearly as selective as it has been reported to be in solution in methanol.

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