v-Triazolines. Part 8. 1-Aryl-4-alkyl- and -aryl-thiomethyl-5-amino-v-triazolines: synthesis and reactions with bases
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 21,p. 2365-2369
- https://doi.org/10.1039/p19770002365
Abstract
A series of 1-aryl-4-alkyl- and -aryl-thiomethyl-5-amino-v-triazolines has been synthesized and characterized. On reaction with bases they underwent amine and/or thiol elimination yielding 1-aryl-4-alkyl- or -aryl-thiomethyl-v-triazoles (2) and 1-aryl-4-methyl-5-amino-v-triazoles (3), respectively. These latter compounds were formed through aromatization of the 4-methylene-v-triazolines (6) arising primarily from the adducts (1) by thiolate elimination.Keywords
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