Preferential solvation in mixed solvents.

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Abstract
The Kirkwood–Buff integrals and the volume-corrected preferential solvation parameters for the first solvation shell of the completely miscible aqueous binary mixtures of 1,3-oxolane, γ-butyrolactone, diethylamine, 1,2-diaminoethane, pyrrolidine, morpholine, N-methylacetamide and N,N,N′,N′-tetramethylurea were calculated from thermodynamic data at the temperatures for which these data were available. The preferential solvation parameters of these and 33 additional mixtures for which they have been published are related to the structures of the co-solvents.

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