Decomposition of an allyl-substituted nitroxide radical
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1142-1143
- https://doi.org/10.1039/c39720001142
Abstract
Decomposition of N-(1,1-dimethylallyl)-N-t-butylaminoxyl (2) gives ButNO, N-(1,1-dimethylallyl)-O-(3,3-dimethylallyl)-N-t-butylhydroxylamine (4), and the corresponding epoxide (7), the latter being obtained only under aerobic conditions; the hydroxylamine (4) is thermally labile and rearranges to NO-di-(3,3-dimethylallyl)-N-t-butylhydroxylamine (10) at 140°.Keywords
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