Concise synthesis of CC-1065/duocarmycin pharmacophore using the intramolecular Heck reaction

Abstract
3-Methyleneindoline derivatives were synthesized by intramolecular Heck reaction of N-allyl-2-iodoaniline derivatives in the presence of Ag2Co3. This method was successfully applied to the synthesis of the CC-1065/duocarmycin pharmacophore.

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