Synthesis of 2,6-Di-O-methyl-D-mannose
- 1 January 1969
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 47 (1) , 31-33
- https://doi.org/10.1139/v69-003
Abstract
2,6-Di-O-methyl-D-mannose was synthesized using the following sequence of reactions: 1,3,4,6-tetra-O-acetyl-2-O-methyl-β-D-mannopyranose → methyl 2-O-methyl-α-D-mannopyranoside → methyl 2-O-methyl-6-O-trityl-α-D-mannopyranoside → methyl 3,4-di-O-acetyl-2-O-methyl-6-O-trityl-α-D-mannopyranoside → methyl 3,4-di-O-acetyl-2-O-methyl-α-D-mannopyranoside → methyl 3,4-di-O-acetyl-2,6-di-O-methyl-α-D-mannopyranoside → 2,6-di-O-methyl-D-mannose. The preparation and properties of derivatives of the 2,6-di-O-methyl-D-mannose are recorded.Keywords
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