Diterpene synthesis. Part 1. Copper(I)-catalysed 1,6-addition of a benzyl grignard reagent to a dienone
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 2840-2844
- https://doi.org/10.1039/p19790002840
Abstract
Copper(I) salts catalyse the 1,6-conjugate addition reaction of m- and p-methoxybenzylmagnesium halides to the monocyclic linear dienone (6) at the expense of 1,2- and 1,4-addition. An improved synthesis of the dienone is reported.Keywords
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