Synthesis of (–)-frontalin from the (2S,3R)-diol prepared from α-methylcinnamaldehyde and fermenting baker's yeast
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 2,p. 241-244
- https://doi.org/10.1039/p19830000241
Abstract
The synthesis of (–)-frontalin (13) from the (2S,3R)-diol (2b), through the intermediacy of the C5(3S,4S) methyl ketone (6) and of the C11 adduct (8), is reported.This publication has 3 references indexed in Scilit:
- Stereospecific synthesis from non-carbohydrate precursors of the deoxy- and methyl-branched deoxy-sugars L-amicetose, L-mycarose, and L-olivomycoseJournal of the Chemical Society, Chemical Communications, 1978
- A Synthesis of (S)-(—)-Frontalin fromd-GlucoseAgricultural and Biological Chemistry, 1976
- Synthesis of one enantiomer, the other enantiomer, and a mixture of both enantiomers of frontalin from a derivative of methyl-α-D-glucopyranosideJournal of the Chemical Society, Chemical Communications, 1976