Molecular-hydrogen, -nitrogen and monohydride derivatives of the structurally characterised dichloro(o-diphenylphosphino-N,N-dimethylaniline)[tris(p-tolyl)phosphine]ruthenium(II) complex
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 830-832
- https://doi.org/10.1039/c39930000830
Abstract
The crystallographically characterised, five-coordinate complex [RuCl2(o-diphenylphosphino-N,N-dimethyianiline){P(p-tolyl)3}] reversibly binds H2 and N2 to form η2-H2 and σ-N2 species, respectively; the former reacts with base to generate the chloro(hydrido) derivative.Keywords
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