Magnetic and Móssbauer investigations of NN-disubstituted dithiocarbamato-iron(II) complexes
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 902-903
- https://doi.org/10.1039/c39730000902
Abstract
Magnetic susceptibility and Mössbauer measurements show the air-sensitive iron(II) compounds, Fe(R2NCS2)2, to be of two different structural types: intramolecular anti-ferromagnetic dimers, e.g., [Fe(Et2NCS2)2]2, involving five-co-ordinate iron, and antiferromagnetic polymers, e.g., [Fe(Me2NCS2)2]n, believed to involve octahedral co-ordination about the metal.Keywords
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