Membrane voltammetry: The interface between two immiscible electrolyte solutions
- 26 November 2001
- journal article
- Published by Royal Society of Chemistry (RSC) in Physical Chemistry Chemical Physics
- Vol. 3 (23) , 5274-5282
- https://doi.org/10.1039/b107463f
Abstract
The voltammetric response obtained when the interface between two immiscible electrolyte solutions (ITIES) is modified by commercially available, track-etched membrane materials is reported. The electrochemical response is consistent with the location of the ITIES within the pores of the membrane material, i.e. ensembles of micro-ITIES are generated by this procedure. The mass-transport phenomena peculiar to these types of interface and prospects for the measurement of interfacial kinetics are discussed.Keywords
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