The intramolecular vibrations of the ammonia water complex. A matrix isolation study
- 1 December 1989
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 91 (11) , 6604-6612
- https://doi.org/10.1063/1.457379
Abstract
The infrared spectrum of the ammonia water complex has been recorded from 10 to 4000 cm−1 for complexes trapped in neon and krypton matrices. Spectra have been observed for NH3 or ND3 complexed with H2O, HDO, or D2O. The observed intramolecular fundamentals are compared with frequencies calculated from a rigid-molecule harmonic oscillator model.Keywords
This publication has 20 references indexed in Scilit:
- Water in krypton matricesJournal of Molecular Structure, 1989
- Far-infrared observations of rotation-tunneling and torsional transitions in the HCl dimerChemical Physics Letters, 1988
- Tunable far infrared laser spectroscopy of van der Waals bonds: Extended measurements on the lowest Σ bend of ArHClThe Journal of Chemical Physics, 1988
- FTIR spectra of ammonia clusters in noble gas matricesThe Journal of Chemical Physics, 1987
- An extended study of the lowest Π bending vibration–rotation spectrum of Ar–HCl by intracavity far infrared laser/microwave double resonance spectroscopyThe Journal of Chemical Physics, 1987
- Vibrational spectroscopy of van der Waals bonds: Measurement of the perpendicular bend of ArHCl by intracavity far infrared laser spectroscopy of a supersonic jetThe Journal of Chemical Physics, 1986
- Characterization of the lowest-lying Π bending state of Ar–HCl by far infrared laser–Stark spectroscopy and molecular beam electric resonanceThe Journal of Chemical Physics, 1985
- Complex between water and ammoniaThe Journal of Physical Chemistry, 1982
- The rotation and inversion of normal and deuterated ammonia in inert matricesJournal of Molecular Spectroscopy, 1977
- The i.r. spectra of matrix isolated water species—I. Assignment of bands to (H2O)2, (D2O)2 and HDO dimer species in argon matrices.Spectrochimica Acta Part A: Molecular Spectroscopy, 1976