The Chemical Attack on Polymeric Materials as Modified by Diffusion
- 1 November 1950
- journal article
- Published by SAGE Publications in Textile Research Journal
- Vol. 20 (11) , 754-760
- https://doi.org/10.1177/004051755002001102
Abstract
The reaction of polymeric media with a chemical reagent generally involves the preliminary diffusion of the reagent through the polymer. The effect of a relatively rapid diffusion of a chemical reagent into a cylindrical fiber on the over all rate of reaction is considered and the equation therefor is derived. The equation is applicable both to the extent of the reaction and to the decay of stress in the polymer, provided that a linear relationship between stress and extent of reaction is assumed.Keywords
This publication has 24 references indexed in Scilit:
- Diffusion-controlled reaction ratesJournal of Colloid Science, 1949
- The Kinetics of the Heterogeneous Reaction between Potassium Permanganate and Wool.The Journal of Physical Chemistry, 1949
- The Treatment of Wool with Acid Permanganate SolutionsJournal of the Society of Dyers and Colourists, 1949
- The Diffusion of Direct Dyes into CelluloseJournal of the Society of Dyers and Colourists, 1948
- XLV. A diffusion problem in which the amount of diffusing substance is finite.—IV. solutions for small values of the timeJournal of Computers in Education, 1948
- XX. A diffusion problem in which the amount of diffusing substance is finite.—II. Diffusion with non-linear adsorptionJournal of Computers in Education, 1948
- The Exchange Adsorption of Ions from Aqueous Solutions by Organic Zeolites. II. Kinetics1Journal of the American Chemical Society, 1947
- The Theory of Permanent Set at Elevated Temperatures in Natural and Synthetic Rubber VulcanizatesJournal of Applied Physics, 1946
- Network Structure and the Elastic Properties of Vulcanized Rubber.Chemical Reviews, 1944
- Theory of the Elastic Properties of RubberThe Journal of Chemical Physics, 1943