Gas phase reactions of CF3, C2F5, and n‐C3F7 with carbon tetrachloride
- 1 November 1984
- journal article
- research article
- Published by Wiley in International Journal of Chemical Kinetics
- Vol. 16 (11) , 1351-1356
- https://doi.org/10.1002/kin.550161107
Abstract
The reactions of some perfluoroalkyl radicals with carbon tetrachloride have been studied using the photolysis of the corresponding perfluoroalkyl iodide as the free radical source. The Arrhenius parameters, based on the value of 2.3 × 1013 cm3 mol−1 s−1 for the self‐combination rate constant of all radicals are: Reaction log(A/cm3 mol−1 s−1) E/kcal mol−1 CF3 + CCl4 12.8 11.3 C2F5 + CCl4 12.8 11.6 n‐C3F7 + CCl4 12.9 12.0Keywords
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