A 1‐Oxa‐2‐nickela‐5‐cyclopentanone from Ethene and Carbon Dioxide: Preparation, Structure, and Reactivity
- 1 August 1987
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 26 (8) , 771-773
- https://doi.org/10.1002/anie.198707711
Abstract
Complex 1 is a key intermediate in the Ni0‐promoted CC bond formation between alkenes and CO2; it contains 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) as ligand. The NiC bond of 1 can participate in further, regioselective insertion reactions with alkenes. The nickelacycle is thus a model complex for the study of Ni‐catalyzed reactions. equation imageKeywords
This publication has 6 references indexed in Scilit:
- CC‐Coupling of CO2 and Butadiene on Iron(0) Complexes—A Novel Route to α,ω‐Dicarboxylic AcidsAngewandte Chemie International Edition in English, 1986
- CC-Kupplung von CO2 und Butadien an Eisen(o)-Komplexen – ein neuer Weg zu α,ω-DicarbonsäurenAngewandte Chemie, 1986
- CC-Verknüpfund von alkenen mit CO2 an nickel(O); herstellung von zimtsäure aus styrolJournal of Organometallic Chemistry, 1986
- Metallacycloalkanes and -alkenesAdvances in Heterocyclic Chemistry, 1986
- Nickel(0)-induzierte CC-verknüpfung zwischen 1,2-dienen und kohlendioxidJournal of Organometallic Chemistry, 1984
- Übergangsmetallkomplexe, I. Olefin‐Komplexe des Nickels(0)European Journal of Organic Chemistry, 1966