Long-Lived Charge-Separated State Produced by Photoinduced Electron Transfer in a Zinc Imidazoporphyrin-C60Dyad
- 1 July 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 5 (15) , 2719-2721
- https://doi.org/10.1021/ol0349256
Abstract
Photoexcitation of a zinc imidazoporphyrin-fullerene dyad with a short linkage results in formation of the charge-separated state by photoinduced electron transfer. The charge-separated state has a lifetime of 310 μs in benzonitrile at 278 K, which is the longest lifetime in solution ever reported for electron donor−acceptor-linked dyads.Keywords
This publication has 13 references indexed in Scilit:
- Exciplex Intermediates in Photoinduced Electron Transfer of Porphyrin−Fullerene DyadsJournal of the American Chemical Society, 2002
- Photochemical and Electrochemical Properties of Zinc Chlorin−C60Dyad as Compared to Corresponding Free-Base Chlorin−C60, Free-Base Porphyrin−C60, and Zinc Porphyrin−C60DyadsJournal of the American Chemical Society, 2001
- Charge Separation in a Novel Artificial Photosynthetic Reaction Center Lives 380 msJournal of the American Chemical Society, 2001
- Biomimetic Electron‐Transfer Chemistry of Porphyrins and MetalloporphyrinsPublished by Wiley ,2001
- Electron‐Transfer Chemistry of FullerenesPublished by Wiley ,2001
- Supramolecular fullerene chemistryChemical Society Reviews, 1999
- Fused porphyrin-imidazole systems: new building blocks for synthesis of porphyrin arraysJournal of the Chemical Society, Perkin Transactions 1, 1999
- C60-Based Electroactive OrganofullerenesChemical Reviews, 1998
- Electron Transfer Reactions in Chemistry: Theory and Experiment (Nobel Lecture)Angewandte Chemie International Edition in English, 1993
- Electron transfers in chemistry and biologyBiochimica et Biophysica Acta (BBA) - Reviews on Bioenergetics, 1985