Beiträge zur Chemie des Bors, 211. Zum Aufbau von Bor‐Germanium‐Bindungen mit Dimethylgermylen
- 1 February 1992
- journal article
- notiz
- Published by Wiley in European Journal of Inorganic Chemistry
- Vol. 125 (2) , 401-405
- https://doi.org/10.1002/cber.19921250217
Abstract
Contributions to the Chemistry of Boron, 211[1]. — On the Formation of Boron‐Germanium Bonds with Dimethylgermylene2‐(Dimethylgermyl)‐1,3,2‐benzodioxaborole (3) is formed by insertion of dimethylgermylene into the BH bond of catechol borane (2). According to the same principle, the trigermylborane 5 is obtained by insertion of three Me2Ge units into the BCl bond of chloro(2,2,6,6‐tetramethylpiperidino)borane (4). Me2Ge reacts with 9‐fluorenylidene(tetramethylpiperidino)‐borane 8 to yield the trigermaborolane 10, which is characterized by an X‐ray structure analysis.Keywords
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