Synthesis of titanium polythioethers
- 1 February 1972
- journal article
- research article
- Published by Wiley in Journal of Polymer Science Part A-1: Polymer Chemistry
- Vol. 10 (2) , 521-531
- https://doi.org/10.1002/pol.1972.150100217
Abstract
The synthesis of polythioethers of the form magnified image was effected, where Cp denotes cyclopentadienyl. Four reaction systems were studied and evaluated. Two proved to be undesirable (the “reverse” interfacial and organic solution methods), while two proved acceptable (the “normal” interfacial and aqueous solution methods). A number of added bases were evaluated. Et3N and NaOH were found to be acceptable. Yield increases with reaction time for aqueous solution syntheses, while yield remains constant with reaction time for synthesis via the normal interfacial method.Keywords
This publication has 11 references indexed in Scilit:
- CONCENTRATESPublished by American Chemical Society (ACS) ,1971
- Production of Organometallic Polymers by the Interfacial Technique. XVI. Importance of Hydrolysis in the Synthesis of Poly[oxyadipoyloxy(diphenylsilylene)]Macromolecules, 1971
- Production of organometallic polymers by the interfacial technique. X. Influence of the nature of base employed on the synthesis of polysilylalkylene (arylene) diaminesJournal of Polymer Science Part A-1: Polymer Chemistry, 1970
- A radiochemical study of bis-(π-cyclopentadienyl)-titanium(IV)-cyclotetrasulfan photolysisJournal of Inorganic and Nuclear Chemistry, 1969
- Reaction vessel with stirring and atmosphere controlsJournal of Chemical Education, 1969
- Notizen: Di-π-cyclopentadienyl-metall-endithiolate der IV. und VI. NebengruppeZeitschrift für Naturforschung B, 1968
- Infrared spectroscopic practicesJournal of Chemical Education, 1968
- Organosulfur derivatives of the metal carbonyls. X. Transition metal derivatives containing both .pi.-cyclopentadienyl and cis-1,2-ethylenedithiolate ligandsInorganic Chemistry, 1968
- Di‐π‐cyclopentadienyl‐titan(IV)‐pentaselenid und ‐pentasulfid, zwei Hetero‐cyclohexachalkogene in fixierter KonformationEuropean Journal of Inorganic Chemistry, 1968
- U¨ber einige π-komplexstabilisierte titan-schwefel-hetero-cyclenJournal of Organometallic Chemistry, 1965