Small changes in work function of the TiC(001) surface with chemisorption of O2 and H2O

Abstract
Changes in work function of the TiC (001) surface have been measured against O2 and H2O exposure by using photoelectron spectroscopy. The sticking rates are about 1/100 of those for elemental Ti‐metal substrate. In the case of oxygen exposure, the work function increases monotonically from 3.8 to 4.2 eV, whereas for H2O a maximum value of work function occurs at an exposure of ∼300L, and its value finally reaches 4.5 eV.

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