Energy barrier for 1,2-hydrogen migration in benzylchlorocarbene
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 982-984
- https://doi.org/10.1039/c39850000982
Abstract
The intermolecular-intramolecular rate constants derived from the thermolysis and photolysis of 3-chloro-3-benzyldiazirine in tetramethylethylene gave an excellent Arrhenius plot; an activation energy of 6.4 kcal mol–1(26.8 kJ mol–1) was obtained for the 1,2-H migration in benzylchlorocarbene.Keywords
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