Optical properties and photoexcitation of a novel liquid form of soluble polyacetylene
- 1 December 1984
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 30 (11) , 6601-6605
- https://doi.org/10.1103/physrevb.30.6601
Abstract
Optical absorption, fluorescence emission, Raman scattering, and time-resolved emission experiments are reported on a new liquid form of soluble polyacetylene. This liquid consists of separate polyene chains, grown on activated sites of a polybutadiene chain. The depolarization ratios as well as the time-resolved spectrum of the secondary emission were measured. The relevant spectral features are discussed and analyzed in terms of the lack of interchain interactions which characterize the polymer in solution.Keywords
This publication has 23 references indexed in Scilit:
- On the optical properties of trans-polyacetyleneThe Journal of Chemical Physics, 1983
- Hot luminescence intrans-polyacetylene: A picosecond time-resolved studyPhysical Review B, 1983
- Soluble polyacetylene graft copolymersMacromolecules, 1983
- On two different approaches to the theory of the resonant Raman effectJournal of Raman Spectroscopy, 1982
- Resolution of controversy concerning the morphology of polyacetyleneNature, 1982
- Polymers with Metal‐Like Conductivity—A Review of their Synthesis, Structure and PropertiesAngewandte Chemie International Edition in English, 1981
- Absorption and Reflection Spectra of Pure and ClSO3H Doped Polyacetylene FilmsBulletin of the Chemical Society of Japan, 1980
- Franck–Condon effects in resonance Raman spectra and excitation profilesThe Journal of Chemical Physics, 1979
- Electronic structure of polyacetylene: Optical and infrared studies of undoped semiconducting and heavily doped metallicPhysical Review B, 1979
- RAMAN SPECTRA OF POLYACETYLENE AND HIGHLY CONDUCTING IODINE-DOPED POLYACETYLENEChemistry Letters, 1978