Total syntheses of (+)-asperlin, (+)-acetylphomalactone and (5S,6S,7R,8S)-asperlin based on the kinetic resolution of 2-furylmethanols
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 3,p. 317-322
- https://doi.org/10.1039/a603209e
Abstract
The total syntheses of (+)-asperlin 1, (+)-acetylphomalactone 2 and (5S,6S,7R,8S)-asperlin 3 have been achieved employing the kinetic resolution of unsymmetric divinylmethanol using modified Sharpless reagents, which produced two oxidation products, as a key step.Keywords
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