Electron spin resonance study of the t-butylperthiyl radical
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 62-63
- https://doi.org/10.1039/c39790000062
Abstract
The e.s.r. spectrum attributed to the t-butylperthiyl radical, ButSS·, has been observed in solution; the radical is characterised by a single line, ΔH= 0·4 mT and giso= 2·025, and it decays by a second-order process with a rate constant, 2kt, of 2 × 108 dm3 mol–1 s–1 at –86°C.Keywords
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