Properties of nematic liquid crystals doped with hydroquinone and p-benzoquinone: Long-term dynamic scattering under dc excitation
- 1 March 1974
- journal article
- research article
- Published by AIP Publishing in Applied Physics Letters
- Vol. 24 (5) , 213-216
- https://doi.org/10.1063/1.1655157
Abstract
The effect of a charge‐transfer complex pair on dynamic scattering (DS) properties in nematic liquid crystals is reported. With the use of a hydroquinone‐quinone complex pair as dopant, more than one‐year continuous dc operation of DS has been achieved. Purification of materials and use of hermetically sealed cells are necessary. Since nematics doped with conventional organic electrolytes do not show long lives under dc operation, a reversible oxidation‐reduction process was found to play a fundamental role in achieving long dc operation lives of DS in the present nematics. The mechanism of the electrochemical process in DS is briefly discussed.Keywords
This publication has 9 references indexed in Scilit:
- Correlation between Chemical and Electrochemical Reactivity and dc Conduction in the Isotropic Phase of a Liquid Crystalline p-Methoxybenzylidene-p-n-butylanilineMolecular Crystals and Liquid Crystals, 1972
- Effect of charge-transfer acceptors on dynamic scattering in a nematic liquid crystalApplied Physics Letters, 1972
- Dynamic scattering life in the nematic compound p-methoxybenzylidene-p′-amino phenyl acetate as influenced by current densityApplied Physics Letters, 1972
- Behavior of a Deionized Liquid Crystal Subjected to Unipolar Injection in Nematic and Isotropic PhaseApplied Physics Letters, 1972
- Dielectric and Resistivity Measurements on Room Temperature Nematic MBBAMolecular Crystals and Liquid Crystals, 1971
- Dynamic scattering: A new electrooptic effect in certain classes of nematic liquid crystalsProceedings of the IEEE, 1968
- Conductivity titrations of charge-transfer complexes in solution—IIElectrochimica Acta, 1966
- Conductimetric titrations of charge-transfer complexes in solutionElectrochimica Acta, 1966
- Molecular Compounds of the Quinhydrone Type in SolutionJournal of the American Chemical Society, 1944