The scavenger problem in diffusion-controlled recombination
- 1 March 1982
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 76 (5) , 2569-2575
- https://doi.org/10.1063/1.443234
Abstract
A systematic and analytic treatment of the recombination probability for a pair of ions in the presence of a homogeneously distributed scavenger is presented. Results for both low and high scavenger concentrations are given for different ranges of the initial separations of the two ions. The low-density expansion corrects some previously published results, while the recombination probability for large scavenger densities is derived for the first time. Approximations, uniformly valid for all initial distances, are constructed and shown to be in excellent agreement with numerical results.Keywords
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