Charge-transfer interactions involving high oxidation state transitionmetal fluorides
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 5,p. 676-678
- https://doi.org/10.1039/dt9720000676
Abstract
Charge-transfer interactions have been observed between NbF5, MoF6, and WF6 and the Group IV compounds MX4(M = Si, Ge, Sn, X = alkyl; M = C, Si, Sn, X = Cl) and between WF6 and C6H6, C6H5CH3, and C6F5. WF5OMe behaves similarly to WF6 but the spectra of phenoxotungsten (VI) fluorides are solvent independent. Photolysis of solutions of WF6 in C6H6, C6H5CH3, and Me4Sn, leads to reduction of tungsten but pure products are not obtained.Keywords
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