Half-sandwich compounds of zirconium(II): the synthesis of [Zr(η6-C7H8)(PMe3)2Cl2]
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 908-909
- https://doi.org/10.1039/c39890000908
Abstract
Reduction of [ZrCI4] in the presence of cycloheptatriene and PMe3 forms [Zr(η6-C7H8)(PMe3)2Cl 2](1), and reaction of iodotrimethylsilane with [Zr(η7-C7H7)(PMe3)2](2), produced from [Zr(η6-C7H8)2](4)via[Zr(η7-C7H7)(tetrahydrofuran)2l](5), forms [Zr(exo-η6-C7H7SiMe3)(PMe3)2l2](3); the crystal structures of (1),(3),and (5) have been determined.Keywords
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