Transition metal imide/organic imine metathesis reactions: unexpected observations
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 16,p. 1669-1670
- https://doi.org/10.1039/a803719a
Abstract
Mixtures of [Ti(NBut)Cl2(py)3] 1 and PhC(NAr)H (Ar = C6H3Me2-2,6 or C6H4Me-4) gave quantitative conversion to [Ti(NAr)Cl2(py)3] and PhC(NBut)H, the products of TiNBut/CNAr transition metal imide/organic imine meta-thesis; examination of the kinetics for Ar = C6H4Me-4 showed that the rate limiting step for this process is zero order in [1], demonstrating that these reactions do not involve metal imide particiption in the rate limiting step.Keywords
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